Synthesis of 3-substituted coumarins via sequential pericyclic transformations of δ-aryloxymethylacrylic acids and enophiles

A new procedure for the synthesis of 3-functionally substituted coumarins via sequential Claisen and ene reactions of δ-aryloxymethylacrylic acids and anophiles has been developed.     

Thermal behaviour of chromium (III) perchlorate hexahydrate

Thermal behaviour of intimate mixtures of chromium(III) oxide and lithium¹, potassium², rubidium³, cesium³ and thallium(I)⁴ perchlorates revealed that chromium(III) oxide not only catalyses the decomposition by lowering the decomposition temperatures of the pure metal perchlorates but also chemically interacts resulting in the formation of metal dichromate. The oxidation of chromium(III) into the hexavalent state is attributed to the abstraction of oxygen from the perchlorate moiety during the decomposition. In this context, it was thought interesting to study the thermal behaviour of chromium(III) perchlorate and to identify the decomposition products in order to find out whether chromium(III) is oxidized into chromium(VI) by the perchlorate group. Except for a report⁵ on the preparation of chromium(III) perchlorate with different molecules of water of hydration no work seems to have been carried out on the thermal decomposition of this compound. In the present study, the decomposition characteristics are followed by TG and DTA techniques and the decomposition products have been examined by chemical analysis, X-ray powder diffraction patterns and infrared spectral measurements.     

STUDIES ON THE INTERACTION OF EPOXY POLYMERS WITH HOMOPOLYUREAS

INTRODUCTION Epoxy resins are reactive polymers which when cured with a variety of chemicals lead to a host of useful thermosets. Since the epoxide is a strained ring, it readily undergoes addition and homopolymerization. The homopolymerization is a process catalysed by acids, bases, Lewis acids, t-amines as well as by inorganic salts.     

Redox polymerization of acrylonitrile. Kinetics of the reaction initiated by systems based on cyanoacetic acid/Mn(III) complexes in dimethylsulphoxide

The kinetics of polymerization of acrylonitrile initiated by the redox systems cyanoacetic acid/Mn(OAc)₃ and cyanoacetic acid/tris(benzoylacetonato)manganese(III) in dimethylsulphoxide as solvent have been investigated over the range 20–35°. The kinetics of oxidation are consistent with the formation of intermediate complexes between the reactants, followed by electron transfer. Manganous ions inhibit the reaction by competitive complexation. The primary radicals are very efficient as initiators of polymerization which is terminated by mutual interaction of macroradicals. Mechanisms have been proposed to explain the kinetics; rate and equilibrium constants have been evaluated.     

Synthesis and structure of a new [6.6]metacyclophane with enediyne bridges

[reaction: see text] Synthesis and structure of a novel [6.6]metacyclophane with enediyne bridges is reported.     

Effect of welding process on fatigue crack growth behaviour of austenitic stainless steel welds in a low alloy (Q & T) steel

Fatigue crack growth behaviour from a lack of penetration (LOP) defect in austenitic stainless steel weld metals of cruciform joints made of a low alloy high strength (Q & T) steel has been studied to understand the effect of two welding processes, namely, shielded metal arc welding (SMAW) and flux cored arc welding (FCAW). Fatigue crack growth studies were carried out at a stress ratio of R = 0 and a frequency of 90 to 110 Hz in a resonant testing equipment (Rumul, Model:8601). Crack growth rates were relatively lower in the weld metal obtained by flux cored arc welding process. Microstructural features observed revealed marked difference in the morphology of delta ferrite for the welded joints obtained from the above two welding processes. Long streaks of delta ferrite in austenite matrix were found in case of SMAW-weld metal which seem to have lowered the resistance to the fatigue crack propagation. A discontinuous network of delta ferrite found in austenite matrix in the case of FCAW-weld metal seems to have contributed to slower propagation of fatigue crack. Fractographic features also substantiate the observed trends in the fatigue crack growth behaviour.     

An extremal problem in geodetic graphs

An upper bound for the number of lines in a geodetic block of diameter d on p points is obtained, using some new general properties of geodetic blocks which are also of independent interest.